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8 Aroma chemicals for beginning perfumers

parker25mv

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Oct 12, 2016
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Some perfumers working with naturals might want to dip their toes in the water and begin using some synthetic ACs, but may not know where to start. The following are a handful of the most commonly used and important ACs used in fragrances. It could be a good place to start experimenting.

1. Linalool - This is sort of along the lines of lavender, but clearer, more transparent.
You could also try linalyl acetate, also beautiful, less sharp than linalool. It may also help give you a sense of the difference between terpenic alcohols and acetates in general.

2. Salicylate - There are several different types of salicylates. You could try any of them (with the exception of methyl salicylate which is very mint-wintergreen, not a good introduction to salicylates). Probably the most common salicylate used in perfumery is Isoamyl salicylate. Salicylates add a white opaque floral effect, reminiscent of the smell of many sunscreens.

3. Iso E Super - This is in the "amber-wood" category.

4. Phenylethyl alcohol - This is so widely used in perfumery. Kind of has a little bit of a sharp feel, reminiscent of a certain part of the smell in rose (maybe more of a wilting rose). If you have smelled certain alcohol sanitary wipes, this is the smell.
It doesn't smell bad, smells kind of interesting, doesn't smell really wonderful on its own, but it can be very useful in some situations. If I had to guess, maybe 30 percent of women's fragrances use some of this.

5. Dihydromyrcenol - This may not smell so wonderful on its own but is extremely useful in perfumery. Kind of gives a deeper darker very textured woody lavender-lime sort of feel. Will often be found in many men's bathroom fragrances adding freshness.

6. C-9 or C-10 aldehyde - Add one of these if you want to add a "sparkling" effect to your fragrance. This is the typical "aldehyde"-type effect. You might try 0.5%.
C-9 leans just a little more sour lemony rose in feel, whereas C-10 leans a tiny bit more orange, but the two are much more similar to each other than different. By themselves, they are kind of waxy soapy feeling, even a little reminiscent of a burning candle.

7. Geraniol - This might be one more you might want to try. It's reminiscent of the green leaves of roses, sort of evoking the effect of a red rose, kind of sharp, it feels "wet and dewy". It's in the terpenic alcohol family like linalool but smells very different.

8. Coumarin - This is very commonly used in fragrances, especially for a sweeter effect. Some compare this effect to a deep dried amber-color hay. This is the "tonka bean" note.
(Warning: be aware that you do NOT want to ingest this. It can act as a poisonous blood thinner. But a little diluted on your skin is perfectly okay)
Maybe try 1 to 2%. You can use up to 5%.

(I want to emphasise that all the above do not smell as complex or wonderful as natural essential oils, but they will provide a much stronger concentrated smell than most essential oils, and are more practical economically. They all play an important role in fragrances, when combined with other natural materials. As a beginning perfumer, I also recommend for most of the florals that you look to synthetic bases, not the naturals, since they will be much stronger in smell and much less expensive than natural flower absolutes.)

You may also want to experiment with adding very small amounts of the ionones, or maybe even damascones/damascenone.
These can really add life and specific character to a fragrance. They are very potent in effect so only need to be added in low levels. You can try the ionone at 1.5%, though it will still have a very noticeable effect at 0.5%. (For damascone, even 0.1% will give a very powerful effect, and it will noticeably change the feel of the fragrance even at 0.01%)

If you want to experiment with musks, try Exaltolide or Ambrettolide at maybe 4 to 7%.

Vanillin can be good to have on hand. It's very similar to vanilla but less complex and sweeter, and it is more concentrated, a little goes a long way. It is cheaper than natural vanilla. Maybe try 0.5 to 1%.

If you combine all the above with natural essential oils, you can start making some perfumes that smell similar to the professional ones (or at least begin to approach the feel of commercial fragrances).
 

Emanuel76

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Jun 16, 2018
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1. I bought all of them (Linalyl Acetate, too), except Linalool. I will use Ho Wood or/and Rosewood instead.

2. I bought Benzyl Salicylate because it's a floraliser. And Amyl Salicylate because I'm short on green-herbal stuffs.

3. Besides Iso E Super, I also bought Sylvamber and Timbersilk. I actually bought many woody-ambers, but, from what I understood, these two would be similar to Iso E Super, though each with its own personality.

5. Grrrrr! Dihydromyrcenol to me is way way down, near Calone (and similar), synthetic musks (overdose) and screatchy woody-ambers (overdose). I bought it though to check how it behaves in minute quantity. I do not know exactly if it was Dihydromyrcenol - I have to check - but even in some perfumes that I really love, I detected in the deep dry down a lemon-metallic odor. Lemon-metallic didn't sound pleasant at all, it's true, but in that context, in a very small dose, it was interesting.

6. I also bought C11. I didn't buy C12 because, from its description, it is exactly the aldehyde that I do not like at all.
 

Emanuel76

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Jun 16, 2018
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I want to test the musks (I bought 33) in two perfumes - one simple and light, one complex and heavy.
Any advices? %?
 

Tharrys78

Member
Apr 22, 2021
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1. I bought all of them (Linalyl Acetate, too), except Linalool. I will use Ho Wood or/and Rosewood instead.

2. I bought Benzyl Salicylate because it's a floraliser. And Amyl Salicylate because I'm short on green-herbal stuffs.

3. Besides Iso E Super, I also bought Sylvamber and Timbersilk. I actually bought many woody-ambers, but, from what I understood, these two would be similar to Iso E Super, though each with its own personality.

5. Grrrrr! Dihydromyrcenol to me is way way down, near Calone (and similar), synthetic musks (overdose) and screatchy woody-ambers (overdose). I bought it though to check how it behaves in minute quantity. I do not know exactly if it was Dihydromyrcenol - I have to check - but even in some perfumes that I really love, I detected in the deep dry down a lemon-metallic odor. Lemon-metallic didn't sound pleasant at all, it's true, but in that context, in a very small dose, it was interesting.

6. I also bought C11. I didn't buy C12 because, from its description, it is exactly the aldehyde that I do not like at all.
First time I smelled DHM I also thought - wow, this is car shampoo, so fake and cheap, this is never going inside my fragrances, maybe in tiny quantities.
Then I found some good cologne accords that was like 60% DHM and... It worked. Still very strong, but the car shampoo mind image wasn't there anymore.
 

Emanuel76

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Jun 16, 2018
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First time I smelled DHM I also thought - wow, this is car shampoo, so fake and cheap, this is never going inside my fragrances, maybe in tiny quantities.
Then I found some good cologne accords that was like 60% DHM and... It worked. Still very strong, but the car shampoo mind image wasn't there anymore.
Which is consistent with the maximum percentage range suggested in the TGSC formulas - 0.05, 0.3, 2, 5, 8%.
I'll try it first at 0.05% though. :D
 

KenA

Member
Jun 11, 2017
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26
I don’t think Iso E Super should be categorized as an “amber-wood”. It’s a very nice aroma compound and it is a woody aroma, but I don’t think it falls into the amber category.

Disclaimer: There is no amber tree, root, plant or animal secretion, so amber is an imagined note. It is supposed to capture in an aroma the translucent golden color of amber gem stones. Traditionally this has been done with labdanum, benzoin and other resins, but there is no standard that defines amber. So every thing I say about amber, or what anyone else says, is personal opinion.

“Amberwood” is listed as a note for many fragrances today which have very prominent notes of “super-amber’ (also not defined, but I think of as ambrocenide, timber propanol, woody dioxolane and others like them). I think of these as being closer to the aroma of oud. Oud and super ambers are very powerful and seem to last longer than forever. The fact that that some of these are inexpensive, are relatively new (different from the mundane) and extend the life of a fragrance incredibly make them popular with perfumers, but I personally hate them. When amberwood is used as a note describe a fragrance, to me it is a very big warning to stay away.

Another aroma compound which is also incorrectly associated with super ambers is ambroxan. Ambroxan doesn’t smell anything like them. I really like the smell of ambroxan, but as I understand it, ambroxan is used in small amounts to act as a fixative and have an effect on the fragrance. It’s not really used as a prominent note and it doesn’t stand out as something people would smell.., even though it is listed as a note. I think that because ambroxan is listed with these fragrances, people are getting the impression that ambroxan smells like a super amber.

I wish there was a different note that could be used for the super ambers. I’ve wasted too much money on blind buys only to learn they have super ambers. It has gotten to the point that I’m very leery if a fragrance if it lists amber as a note.
 

Emanuel76

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Jun 16, 2018
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I don’t think Iso E Super should be categorized as an “amber-wood”.

Another aroma compound which is also incorrectly associated with super ambers is ambroxan.
I totally agree.
Yet sometimes I let it slide, because many consider them so.
 

Emanuel76

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Jun 16, 2018
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Wait! Kephalis, Ambermax, Ambrocenide, Amber Core etc are all mislabelled as woody-amber?! Do these also have no amber at all? :oops:
 

KenA

Member
Jun 11, 2017
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26
IMG_2472.jpeg
This amber accord is from the Perfumers Apprentice website. I used this recipe to make it myself 5 or 6 years ago. When I was finished, I hated it. It is 10% okumal. As I added the additional ingredients after okoumal, I was looking for the magic to happen and a nice amber to emerge.., but it never happened. To me, the final accord smelled like okumal. It was about the same time I started paying attention to fragrances and started noticing the new, not so good, concept of amber. … Notice how much amboxan is used (.005%). I know people can smell geosmin at such low levels and maybe there are other aroma compounds that can be smelled at that level, but I don’t think ambroxan is one of them. I don’t think a lot of people posting about ambroxan on basenotes know what it smells like, but I don’t blame them, I believe it is because of all the mislabeling.
 

parker25mv

Well-known member
Oct 12, 2016
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2. I bought Benzyl Salicylate because it's a floraliser.
It is a floraliser but not a very strong one. The smell of benzyl salicylate is surprisingly weak (I mean for a salicylate).
It's not a bad one to have, but probably not the best introduction.

6. I also bought C11. I didn't buy C12 because, from its description, it is exactly the aldehyde that I do not like at all.
The two are very similar. (Almost more just like little nuances a little bit in different directions)

Amber Key Accord
It's true that what passes as "amber" can be open to a little bit of interpretation.

I think that's probably a separate long discussion though.
 

Emanuel76

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Jun 16, 2018
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Reactions : 🤣 KenA
Why are you laughing, Ken?
So, it's true?
That's tragic. I was really hoping those 4 were really amber (-wood). I mean Ambermax, Ambrocenide, Amber Core, FFS.
I'm disappointed. :cry:
They'll arrive tomorrow.

View attachment 332747
This amber accord is from the Perfumers Apprentice website. I used this recipe to make it myself 5 or 6 years ago. When I was finished, I hated it. It is 10% okumal. As I added the additional ingredients after okoumal, I was looking for the magic to happen and a nice amber to emerge.., but it never happened. To me, the final accord smelled like okumal. It was about the same time I started paying attention to fragrances and started noticing the new, not so good, concept of amber. … Notice how much amboxan is used (.005%). I know people can smell geosmin at such low levels and maybe there are other aroma compounds that can be smelled at that level, but I don’t think ambroxan is one of them. I don’t think a lot of people posting about ambroxan on basenotes know what it smells like, but I don’t blame them, I believe it is because of all the mislabeling.
Well, the formula looked pretty bad right from the bat, not at all to my taste. I don't understand why it surprised you.

Galaxolide 20% (without Ethanol), Exaltolide 10%, Okoumal 10%, Velvione 5% -> 56.25% musks !!!, because aMbEr.
JFC!

You have plenty of good formulas to make and to be inspired by, here, or on TGSC.

For example:

376.3 - labdanum resinoid
19.80 - patchouli oil
99.00 - siam benzoin resinoid
49.50 - vetiver oil bourbon
99.00 - sandalwood oil
19.80 - oakmoss absolute 50%
49.50 - musk ambrette replacer
49.50 - musk ketone
49.50 - vanillin
69.30 - bergamot oil bergaptene reduced
49.50 - orange peel oil c.p. california
49.50 - rose 392/2 (Givaudan)
9.90 - castoreum absolute 10%
9.90 - laitone

A pile of Labdanum - checked
A pile of other good stuffs - checked
A bit of Castoreum for depth - checked
Not a pile of musks - checked
A bit of Laitone for creaminess - checked

If I understood correctly, Methyl Laitone is only sold at a 10% concentration, so, since they didn't specify the dilution, I assume that that quantity will have to be multiplied by 10 and the amount of diluent taken into account.

Well, it looks very well to me.
I do not understand, however, why in many base formulas are used citrus? Citrus are top notes. What's the catch?

Okoumal
Odor Description:Woody, Ambery, Tobacco, Musky
Okoumal gives significant volume, richness and warmth to fragrance compositions at a reasonable dosage. As little as 0.5 - 1% adds an attractive, woody-ambery effect. Okoumal combines well with cedar derivatives, patchouli oil and sandalwood products (eg. Ebanol). With its low vapour pressure and high MW, Okoumal is a body note and is extremely long lasting (more than 1 month) and substantive on every support. Okoumal is very stable in major applications.

Woody - myeah
Ambery - not at all
Tobacco - yeah, I can see that
Musky - hell yeah
Warmth - true

Okoumal is similar to a musk. It has a ferm, a more solid type of fluffiness. On a scale from dandelion to felt, it's closer to felt, unlike Galaxolide, for example, which when overdosed, turns towards dandelion.
It's true, Okoumal cannot be overdosed, because it has a much stronger odor than Galaxolide, which after a while, is just texture/effect, not odor (almost) at all (Galaxolide).

I think it would work well with patchouli.
With wood probably it can be used as a good sawdust maker (if you like that effect), due to it's more ferm texture.
I don't like sawdust at all.

I didn't like Okoumal at all for the first time, but now I think it can be useful.
I'll definitely test it in an ambergris accord, because it's warm, its texture, a vague salty impression and for its radiance/projection.

With its low vapour pressure and high MW, Okoumal is a body note and is extremely long lasting (more than 1 month) and substantive on every support.
This part is interesting. I have to look into what this is about.
What is MW?
 
Last edited:

parker25mv

Well-known member
Oct 12, 2016
2,709
621
I do not understand, however, why in many base formulas are used citrus? Citrus are top notes. What's the catch?
It's common and ordinary for statements to be made that are not totally accurate in all ways, to oversimplify things.
Many notes, such as citrus, have separate components in them that fit into different categories. But it's just easier to say citrus is a top note. Probably because most of its character is a top note, and citrus loses a lot of its distinctiveness after its limonene component evaporates away.
 

Casper_grassy

Well-known member
May 5, 2020
2,041
1,215
What is MW?
Molecular Weight.

The “Laitone” listed has a different CAS no. and maybe a different odor than methyl laitone. I also don’t know if it is subbed with the methyl version how it’ll differ if it all. If you have methyl laitone 10% then just put it in at that amount and see how it goes.

The citruses/rose are used to make it a seamless “top to bottom” base while adding variety to it. There’s a strong chance they may even go unnoticed in this and if you don’t want them, don’t use them.

Benzyl Salicylate changes odors quite easily, yes it doesn’t smell strong in isolation but it works wonders in formulas and it is one of the best salicylates you can use.

Last thing, in regards to ambers, there are 100’s of materials where their description says “XYZ” because it can be directed that way, doesn’t mean it IS that way.
Does Eugenol smell like Ylang Ylang? No, but it’s a part of it and it would be a nice addition to an Ylang accord.
 

KenA

Member
Jun 11, 2017
15
26
Why are you laughing, Ken?
I may have misunderstood you. I thought you were being facetious.
Well, the formula looked pretty bad right from the bat, not at all to my taste. I don't understand why it surprised you.
I was just starting to tinker with fragrances and was more ignorant than I am now. I would have, and still do, made other newbies look like seasoned professionals. I’m a software engineer (over 40 years and still working) and I started tinkering to satisfy my curiosity.

I can understand using notes such as “amber” and “woody” to describe these aroma compounds. Words are all we have and we describe everything in similar fashion. I don’t think things can be assumed to be representative of the adjectives used to describe them.

In retrospect, I realize that I have gotten off topic with my frustration over labeling. As I understand it, there is a difference between notes the adjectives used to describe the notes. It seems to me that “amber”, “amberwood” and “ambroxan”are being used as notes for the compounds I call “super ambers”. I don’t think of them as amber, but I realize they are being categorized as such.
 

Emanuel76

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Jun 16, 2018
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It's common and ordinary for statements to be made that are not totally accurate in all ways, to oversimplify things.
Many notes, such as citrus, have separate components in them that fit into different categories. But it's just easier to say citrus is a top note.
Orange peel oil, yes, probably it has decent longevity. But I had the impression the bergamot essential oil is very fleeting.
That's because:
Probably because most of its character is a top note, and citrus loses a lot of its distinctiveness after its limonene component evaporates away.
Yeah, you're right here.

And also because I usually use very little, like one drop on my wrist. But yesterday I generously poured bergamot on my wrist. And after 3 hours it was still there - a velvety bitterness.
 

Emanuel76

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Jun 16, 2018
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Complex and heavy
Shangralide 15
Musk ketone 20
Habanolide 30
Muscenone 40
Edenolide 20
Velvione 5
Petitgrain bigarade 10
C12 MNA 0.5
C10 0.3
Thank you very much!
It looks very good. I have them all, except Musk Ketone, of course, for which I will use substitute (blend).

=====

I wanted to say that I would make two perfumes to test al the Musks (one Musk at a time), one light perfume and a heavy one. I wanted to know in what percentage of the total concentrate to use the musks.
5% for the light perfume and 10% for heavy is that OK?
 

Emanuel76

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Jun 16, 2018
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Molecular Weight.

The “Laitone” listed has a different CAS no. and maybe a different odor than methyl laitone. I also don’t know if it is subbed with the methyl version how it’ll differ if it all. If you have methyl laitone 10% then just put it in at that amount and see how it goes.

The citruses/rose are used to make it a seamless “top to bottom” base while adding variety to it. There’s a strong chance they may even go unnoticed in this and if you don’t want them, don’t use them.

Benzyl Salicylate changes odors quite easily, yes it doesn’t smell strong in isolation but it works wonders in formulas and it is one of the best salicylates you can use.
Thank you!

Last thing, in regards to ambers, there are 100’s of materials where their description says “XYZ” because it can be directed that way, doesn’t mean it IS that way.
Does Eugenol smell like Ylang Ylang? No, but it’s a part of it and it would be a nice addition to an Ylang accord.
It would make sense.
But the problem is that, for example, at Okoumal, on the Givaudan website it says:
Okoumal™ brings an attractive and elegant woody-ambery effect.

On TGSC:
Odor Description: Woody, Ambery, Tobacco, Musky
Not "potential uses". But "odor description".

Combined with the fact that everyone calls them "woody-ambers", it's confusing.
But now I know.
 

ScentAle

Well-known member
Oct 26, 2021
911
463
I have all the musks.
I don't have C12, but I'll use C11 instead.

The aldehydes and Petitgrain Bigarade are to balance the heaviness?

They do create a stronger musk effect, for me very useful mostly in fougere making. The effect of bitter petitgrain and that aldehydes, especially with high shangralide dose, compliment very well for me, also in higher amount. Giving life to musks
 

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